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Código Python:
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from Tkinter import * import os ventana = Tk() titulo = Label(ventana, text="Programas") titulo.pack() def skype(): os.system(r'"C:\Program Files (x86)\Skype\Phone\Skype.exe"') abrir_skype = Button(ventana, text="Skype", command=skype) abrir_skype.pack() ventana.mainloop()