Prueba asi:
Código PHP:
<?php
session_start();
if(!isset($_SESSION['s_username'])){
header("location: entrar.html");
}else{
?>
<!DOCTYPE html PUBLIC "-//W3C//DTD XHTML 1.0 Transitional//EN" "http://www.w3.org/TR/xhtml1/DTD/xhtml1-transitional.dtd">
<html xmlns="http://www.w3.org/1999/xhtml">
<head>
<meta http-equiv="Content-Type" content="text/html; charset=utf-8" />
<title>Untitled Document</title>
</head>
<body>
<p>hola mundo </p>
</body>
</html>
<?
}
?>
a ver que pasa